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Laboratory studies of rock rheology rely on purpose-built devices that can apply planetarily relevant pressures, temperatures, and non-hydrostatic stresses. Generating these pressures and stresses requires the application of large forces over small specimen areas. However, because rocks are generally polymineralic and deformation microstructures form across many length scales, it is advantageous to study relatively large (millimetric) specimens. In addition, many microstructures continue to evolve with progressive strain, so it is vital that some apparatus are able to generate enough shear strain to study these deformation phenomena. This contribution describes two new rock deformation apparatus—the Large Volume Torsion apparatus—at Washington University in St. Louis, which are capable of deforming geological specimens at high pressure and temperature (P = 3 GPa; T = 1800 K). Deformation is imposed in a torsional geometry, which enables the generation of extremely large shear strains (γ > 100) relevant to Earth’s plate boundaries and convecting mantle. A large specimen (diameter up to 4.2 mm) permits detailed postmortem microstructural analysis. Apparatus design, calibration, experimental procedures, and some examples of applications are reviewed. 

SUMMARY The occurrence of plate tectonics on Earth is rooted in the physics of lithospheric ductile weakening and shear-localization. The pervasiveness of mylonites at lithospheric shear zones is a key piece of evidence that localization correlates with reduction in mineral grain size. Most lithospheric mylonites are polymineralic and the interaction between mineral phases, such as olivine and pyroxene, especially through Zener pinning, impedes normal grain growth while possibly enhancing grain damage, both of which facilitate grain size reduction and weakening, as evident in lab experiments and field observations. The efficacy of pinning, however, relies on the mineral phases being mixed and dispersed at the grain scale, where well-mixed states lead to greater mylonitization. To model grain mixing between different phases at the continuum scale, we previously developed a theory treating grain-scale processes as diffusion between phases, but driven by imposed compressive stresses acting on the boundary between phases. Here we present a new model for shearing rock that combines our theory for diffusive grain mixing, 2-D non-Newtonian flow and two-phase grain damage. The model geometry is designed specifically for comparison to torsional shear-deformation experiments. Deformation is either forced by constant velocity or constant stress boundary conditions. As the layer is deformed, mixing zones between different mineralogical units undergo enhanced grain size reduction and weakening, especially at high strains. For constant velocity boundary experiments, stress drops towards an initial piezometric plateau by a strain of around 4; this is also typical of monophase experiments for which this initial plateau is the final steady state stress. However, polyphase experiments can undergo a second large stress drop at strains of 10–20, and which is associated with enhanced phase mixing and resultant grain size reduction and weakening. Model calculations for polyphase media with grain mixing and damage capture the experimental behaviour when damage to the interface between phases is moderately slower or less efficient than damage to the grain boundaries. Other factors such as distribution and bulk fraction of the secondary phase, as well as grain-mixing diffusivity also influence the timing of the second stress drop. For constant stress boundary conditions, the strain rate increases during weakening and localization. For a monophase medium, there is theoretically one increase in strain rate to a piezometric steady state. But for the polyphase model, the strain rate undergoes a second abrupt increase, the timing for which is again controlled by interface damage and grain mixing. The evolution of heterogeneity through mixing and deformation, and that of grain size distributions also compare well to experimental observations. In total, the comparison of theory to deformation experiments provides a framework for guiding future experiments, scaling microstructural physics to geodynamic applications and demonstrates the importance of grain mixing and damage for the formation of plate tectonic boundaries. 

Abstract Antigorite is a hydrous sheet silicate with strongly anisotropic seismic and rheological properties. Hydrous minerals such as antigorite have been invoked to explain numerous geologic observations within subduction zones including intermediate‐depth earthquakes, arc volcanism, the persistent weakness of the subduction interface, trench‐parallelSwave splitting, and episodic tremor and slip. To understand how the presence of antigorite‐bearing rocks affects observations of seismic anisotropy, three mylonites from the Kohistan palaeo‐island arc in Pakistan were analysed using electron backscatter diffraction. A fourth sample, which displayed optical evidence for crystallographically controlled replacements of olivine, was also investigated using electron backscatter diffraction to identify potential topotactic relationships. The resulting data were used to model the bulk seismic properties of antigorite‐rich rocks. The mylonitic samples exhibit incredibly strong bulk anisotropy (10–20% for the antigorite + olivine). Within the nominally undeformed protomylonite, two topotactic relationships were observed: (1) (010)ant//(100)ol with [100]ant//[001]ol and (2) (010)ant//(100)ol with [100]ant//[010]ol. However, the strength of a texture formed by topotactic replacement is markedly weaker than the strength of the textures observed in mylonitic samples. Since antigorite is thought to be rheologically weak, we hypothesise that microstructures formed from topotactic reactions will be progressively overprinted as deformation is localised in regions with greater percentages of serpentine. Regions of highly sheared serpentine, therefore, have the potential to strongly influence seismic wave speeds in subduction settings. The presence of deformed antigorite in a dipping structure is one explanation for observations of both the magnitude and splitting pattern of seismic waves in subduction zones. 

Abstract Quartz is an abundant mineral in Earth's crust whose mechanical behavior plays a significant role in the deformation of the continental lithosphere. However, the viscoplastic rheology of quartz is difficult to measure experimentally at low temperatures without high confining pressures due to the tendency of quartz (and other geologic materials) to fracture under these conditions. Instrumented nanoindentation experiments inhibit cracking even at ambient conditions, by imposing locally high mean stress, allowing for the measurement of the viscoplastic rheology of hard materials over a wide range of temperatures. Here we measure the indentation hardness of four synthetic quartz specimens and one natural quartz specimen with varying water contents over a temperature range of 23°C to 500°C. Yield stress, which is calculated from hardness but is model dependent, is fit to a constitutive flow law for low‐temperature plasticity to estimate the athermal Peierls stress of quartz. Below 500°C, the yield stresses presented here are lower than those obtained by extrapolating a flow law constrained by experiments at higher temperatures irrespective of the applied model. Indentation hardness and yield stress depend weakly on crystallographic orientation but show no dependence on water content. 

Abstract Experimentally quantifying the viscoplastic rheology of olivine at the high stresses and low temperatures of the shallow lithosphere is challenging due to olivine's propensity to deform by brittle mechanisms at these conditions. In this study, we use microscale uniaxial compression tests to investigate the rheology of an olivine single crystal at room pressure and temperature. Pillars with nominal diameters of 1.25 μm were prepared using a focused ion beam milling technique and were subjected to sustained axial stresses of several gigapascal. The majority of the pillars failed after dwell times ranging from several seconds to a few hours. However, several pillars exhibited clear evidence of plastic deformation without failure after 4–8 hr under load. The corresponding creep strain rates are estimated to be on the order of 10⁻⁶to 10⁻⁷ s⁻¹. The uniaxial stresses required to achieve this deformation (4.1–4.4 GPa) are in excellent agreement with complementary data obtained using nanoindentation techniques. Scanning transmission electron microscopy observations indicate that deformation occurred along amorphous shear bands within the deformed pillars. Electron energy loss spectroscopy measurements revealed that the bands are enriched in Fe and depleted in Mg. We propose that inhomogeneities in the cation distribution in olivine concentrate stress and promote the amorphization of the Fe‐rich regions. The time dependence of catastrophic failure events suggests that the amorphous bands must grow to some critical length scale to generate an unstable defect, such as a shear crack.